|
In studying the challenges of burning wood in an open fireplace, pressure
is constant and can be ignored for now, temperature will change and increase
as the exothermic reaction gets going and the trick is to capture and
contain as much of the heat as possible within the combustion zone, and
transfer that heat into the room, not the chimney.
By
positioning the wood as shown (left), and minimizing underfire air, a
great deal of the heat generated in the combustion zone is retained. The
surfaces of the logs glow and radiate heat, also burning up particulates
as in an "after-burner".
The comwbustion heat converts itself to the infrared end of the spectrum
of light, the same spectrum that heats the earth from the sun. Due to
the concave arrangement of the stacked wood, heat is thrown out into the
room, much as a concave mirror magnifies the image it reflects.
On the surface of the earth, we are all dependent on the heat energy from
the Sun for our existence. It takes about one million years for this heat
to reach us after it is formed.
To a large extent the Sun is a ball of Hydrogen formed some 5 billion
years ago. Heat is developed when Hydrogen fuses with Helium. The temperature
increases outwards in the Sun's upper atmosphere reaching temperatures
of around 1 million degrees Kelvin.
Fossil fuels contain solar energy stored from bygone ages. Wood is dependent
on the sun for growth and trees belong to seed bearing plants, coniferous
or softwoods (Gymnospermae) and hardwoods (Angiospermae).
Wood is composed of elongated cells, most of which are oriented in the
longitudinal direction of the stem, which is why wood seasons from the
ends regardless of size, and at the same rate. Wood will not season any
faster if split into smaller pieces, wood is split for sizing not seasoning.
These cells consist mainly of cellulose, hemicellulose and lignin, all
of which are organic and combustible.
Inorganic constituents exist in the bark of trees amounting to 2-5% of
dry bark weight (determined as ash). It is from this bark that dioxins,
furans and other undesirable emissions originate.
Heating wood in the absence of oxygen is called pyrolysis and in the
19th century the process was used to produce methanol, turpentine, acetic
acid, phenols and wood tar, all of which are organic or carbonaceous and
combustible. Heating wood to just above 100 degrees Centigrade initiates
some thermal decomposition, above 250 degrees it becomes more active and
above 270 degrees it is exothermic, producing more and more heat.
During this heat increase, the process produces a mixture of Carbon Monoxide,
Hydrogen, Methane and other gasses which can be burned to produce heat,
or flashed off with other unburned bi-products.
The trick in a home heating appliance is to burn all of these bi-products
and waste nothing, cutting back on harmful emissions in the process. For
all practical purposes, we human beings live at the bottom of an ocean
of air comprising 79.1% nitrogen and 20.9% oxygen, requiring oxygen to
breathe and survive and burn wood, fossil fuels and operate vehicles.
Trees and vegetation convert Carbon Dioxide back to oxygen in a process
known as photosynthesis, contributing to the life cycle. When burning
wood or fossil fuels, specific chemical reactions have been established
and the behaviour of the bi-product gasses defined.
For example, burning 1 lb of carbon in wood will require 11.5 lbs of air,
resulting in 31.4 cubic feet of Carbon Dioxide and 119 cubic feet of Nitrogen.
From the 17th century onwards, work has been done by Boyle, Gay-Lussac,
Avogadro, Dalton, Graham, Van der Waals and others to determine the behaviour
of gasses under temperature and pressure changes and these factors all
exist in open fireplaces and woodstoves when wood is burned.
G.R. Telfer/RONJAN Inc/FIREGRATES 'R Us Inc.
24 January 2002.
|